I may have something to add on the stability of WiFi iOS device connections to iTunes 11.1 on Windows 7 64bit machines and iPv6.
A couple of days ago, not long after my last post, I noticed iPv6 timeout errors for the Bonjour Service in the Windows Event Viewer after observing erratic connections of my iOS7 devices to iTunes 11.1 as I have described previously. In fact as *a lot* of users have described in Apple & other forums for most of the past serveral years.
I had switched off IPv6 on my Windows PC ethernet adaptor some months ago while attempting to troubleshoot the issue as a number of articles online attributed these type of errors to the Bonjour service 'choking' on iPv6, suggesting it was best to disable iPv6 at the Windows adaptor. In my case my Windows PC is connected by ethernet to the same router which serves WiFi to my iOS devices.
However this time I tried enabling iPv6 on the Windows PC adapter and voila! stable "Sync Now' connections for the past few days for *both* my IPhone5 (iOS7) and iPad2 (iOS7) to the same instance of iTunes 11.1 / same Windows 7 64bit PC.
What's more when I again switched-off iPv6 on the adaptor (ie. in order to test reproduceability of this observation) I saw an immediate return to the previous unstable behaviour with iTunes momentarility showing both iOS device connections, then dropping one connection when the second device was synced.
This suggests to me that the (presumably) updated Bonjour Service now being rolled out with iTunes 11.1 requires iPv6 connectivity to reliably support 2 or more iOS devices connected by WiFi to the same Windows machine.
iTunes appears to try using iPv4 connections when iPv6 is not available, but it seems iPv6 connectivity is required to maintain stable connections to multiple devices. This also seems to fit with some of the online technical documents I have read about Bonjour which suggests that iPv6 is used to maintain mulitple connections over a single interface.
Incidentally I don't dispute that turning-off iPv6 may have helped resolve connectivity issues for some users with previous versions of iTunes, particularly if they were only attempting to connect a single device, however I suspect iPv4 and iPv6 behavior has been altered in the lastest version of iTunes & so that it now requires iPv6 to be active on the Windows adaptor if 2 or more devices are connected.
I would be interested to hear if other users experiencing unstable 'Sync Now' connections between their Windows PC and their iOS devices can verify my experience.