I had the same problem with mine. Even went through today's update to 7.1, still didn't make a difference. After scouring the forums and not finding a solution, I finally opened an applecare chat. After several hours with them, I finally just unsynced my photos, and everything worked. The photos on my phone are still there, and the photos on my mac are still there, but the 2 can't be synced right now for some reason. They are having it pushed up to engineering so it can be handled, but that solution worked for me.
All the steps: (mac only)
1. Update all your software. I was pushing iTunes 11.1.5, mac osx 10.9.2, and iOS 7.1
2. Open Image Capture. Down on the bottom left, there's a box for "connecting this iPhone opens:" and select no application. Close Image Capture.
3. Open iTunes, unselect Sync Photos.
4. Run your sync.
That solved it for me until Apple can get a complete fix. Hopefully, it'll work for some of you.