Following up after a couple of months:
In general WiFi sync has worked for me since November and iOS 8.1.2.
However, I've noticed two incidents a couple of weeks apart that were so nearly identical that I'm suspicious that the same thing happened.
First, my iPhone 6 went missing from iTunes. Plugging it in with USB-Lightning cable worked fine, but it dropped off the list as soon as I unplugged it.
Second, my iPhone 6 wasn't updating Reminders. On checking, I found it would not accept my iCloud password. Powering the iPhone down and back up fixed the problem without any further action. In other words, I wasn't logged out of iCloud, the phone just couldn't contact it. Reminders immediately updated after the restart. In addition, as soon as I got home, my iPhone 6 appeared in iTunes.
In both cases, other functions, such as phones, all apps (that I used), LTE, etc. worked fine.