How does your PC boot? Legacy MBR or UEFI? Does your PC have an optical drive?
It used to be really easy making a Windows UEFI booting USB using macOS, but now that one of the Window's installer files is over 4GB in size it has become more difficult. I tried making a Windows 10 USB boot disc a year or so ago shortly after the Win10 installer included a 4GB+ file, but I was unable to get the PC to boot regardless of how I made the Win10 USB installer. I'm usually pretty good about figuring this out, but I had to give up due to time constraints. If you search online you will find instructions for splitting the 4GB file into two separate files (I did so using a Linux utility - may be able to access on a Mac using Homebrew), to use exFAT or NTFS for the USB installer, use a Linux USB boot disk with support for booting .iso files, and even apps to create a bootable Win10 USB installer from the Win10 .iso file. I think success depends on exactly what PC you have since each PC BIOS contains so many quirks.
I forget how I created a bootable Windows USB installer from an .iso using Linux. I may have some notes stored somewhere.