Hi Bill.
Sorry to hear that you are still struggling, please read the following notes and follow my suggestions exactly in the order written.
I haven’t tested GC on my office iMac, for some reason that website is blocked by our universities web server and it can take weeks for me to get these blocks lifted, not having any .pcd source disks at home I can’t test either program on my personal iMac Pro at home either.
I can verify though that both XnViewMP and Graphic Converter are known to work with macOS, particularly XnViewMP , which is working here in my office today on a 2017 iMac Pro running macOS Monterey, and I can read an old Kodak .pcd disk I found in the Geology dept’s archive.
So the problem must be with your Mac, or possibly the installation process.
I see that you are using macOS Catalina?
Try these steps exactly as described.
Drag the XnViewMP application out of the Application folder and into the Bin.
Find the XnViewMP installer in your Downloads folder and delete it.
Empty the Bin.
Reboot the Mac.
Download a fresh copy of the XnViewMP application from the XnViewMP website.
Disable your AV software.
Run the installer for XnViewMP.
Answer the pop-up security question from the Mac Gatekeeper when it warns you the that the App was downloaded from the internet and do you want to open it with “Yes”, or “ok”.
After XnViewMP is installed, exit the installer and launch the program.
At first launch you should see three pop-up questions asking you to allow XnViewMP to access your desktop, downloads and documents folders, answer each pop-up with Yes.
Is the XnViewMP app running now or is its icon still bouncing on the Dock?
If XnViewMP still will not open did you try booting your Mac into Safe-Mode as I suggested earlier?
If you did not try that step please do that next, follow this link for guidance:
https://support.apple.com/en-gb/HT201262
Safe-Mode is a necessary standard fault-finding stage in problem diagnosis and is completely benign.
Safe-Mode is slow to launch, it can take up to ten minutes to reach your user desktop so please be patient.
When Safe-Mode has booted to your desktop can you now launch XnViewMP?
While in Safe-Mode your inputs via mouse and keyboard may appear slow and “laggy”, this is normal, just take your time and see if XnViewMP will start.
If XnViewMP opens in Safe-Mode you have two options.
While still in Safe-Mode you can open your .pcd disks and use XnViewMP to batch convert the contents to .jpg or .tiff format and store that content in your document folder for access later after you reboot the Mac, or, close XnViewMp and reboot the Mac then see if XnViewMP will run properly after the reboot.
If XnViewMP will not run in Safe-Mode either, and the icon continues to bounce on the Dock, then the suspicion must be that your macOS is damaged and the recommended next step would be to boot the Mac into Recovery-Mode and reinstall the macOS.
Reinstalling the macOS in Recovery-Mode keeps all your data and apps intact and requires no complex knowledge, the steps are clearly explained here:
https://support.apple.com/en-gb/HT201314
The only proviso is that reinstalling the macOS in Recovery-Mode may sometimes reveal previously hidden and unknown disk errors that result in the disk requiring a full wipe and clean install of the macOS, in these cases you will need a Time Machine backup to recover your important documents and applications from, after the clean install.
The steps for re-installing the macOS are clearly described in the document I linked to above, and require no special “computer” skills however if you feel this is going to be too demanding then the only remaining options are to book a visit to the technicians at your local Apple Store, where they will be able to resolve this problem for you, or, find a local independent Apple technician (or experienced Apple user) to help you in person.
I don’t think there is much else we, as a remote community, can offer by way of direct help since we can not see what is happening with your machine.
Anyway, try the above steps, at least as far as Safe-Mode, and let us know if that changes the outcome.
Will.