I am suddenly experiencing this problem with Big Sur, too. These extensions - 1Password, Evernote Clipper and Capital One Shopping - are installed and working, but their icons are invisible in the toolbar. When my mouse hovers over their location in the toolbar, a faint grey icon-shaped patch appears, along with the extension name. In the Customise Toolbar interface, these extensions appear, but as faint grey blobs, not as icons. Uninstalling/reinstalling makes no difference. Rebooting makes no difference. Zapping the PRAM makes no difference. These are the only extensions I use which are installed in the Applications folder as Apps.
Any ideas?