Add me to the list of frustrated users experiencing this issue. My wi-fi syncing used to work flawlessly, but has been completely erratic for several months. Because I charge my devices daily I used to know that they were always synced and backed up. Now, not so much. They can go weeks before I realize that syncing hasn't happened.
One interesting thing I noticed:
Even when iTunes and my iPhone cannot "see" one another for wi-fi sync, the Remote app on my iPhone is able to see and connect to iTunes.
System specs:
- iPhone 4S with iOS 6.0.1
- Mac Mini with OS X 10.7.5
- iTunes 11.0.1
- Airport Extreme running Airport Utility 6.1
My iPhone had not synced in 4 days.
My troubleshooting steps:
- Attempt 1: Try to trigger a manual sync via Settings > General > iTunes Wi-Fi Sync
- Result: iPhone cannot find my computer
- Attempt 2: Quit iTunes on my computer and restart iTunes, then trigger a manual sync via the iPhone
- Result: iPhone cannot find my computer
- Attempt 3: Power off iPhone and power back on again, then trigger a manual sync via the iPhone
- Result: iPhone cannot find my computer
- Attempt 4: Open the Remote app on the iPhone and connect to iTunes on my computer (success), then trigger a manual sync via the iPhone
- Result: iPhone cannot find my computer
- Attempt 5: Reboot my compter, then trigger a manual sync via the iPhone
- Result: iPhone finds my computer and syncs correctly
If past experience is any indication this will work for a day or so, then stop working until I reboot again.